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In most cases, bromate (BrO₃–) is formed by the reaction of ozone (O₃) with bromide (Br–) in water. Bromate may be present as a by-product in the production of chlorine gas, and bromate can form if bromide reacts with chlorine in an open reservoir. Normally, the formation of bromate in open reservoirs in the presence of organic material ultimately results in the formation of bromoform (CHBr₃) (learn more about bromoform in our Trihalomethane page). Bromate formation in disinfected drinking water is influenced by factors such as bromide ion concentration, pH of the source water, and the amount of ozone and the reaction time used to disinfect the water. In most cases, this is a concern for bottled water sources that more commonly use ozone as a disinfection agent.
Bromate becomes a problem when bromide present in the water reacts with ozone or as a contaminant in the hypochlorite solution used in the water treatment. If you are considering the installation of an ozonation system, it is strongly recommended to have the water tested for bromide after it has been treated with ozone.
Very high levels of bromate, well above the drinking water standard, are associated with nausea, abdominal pain, effects to the nervous system and kidneys, hearing loss, and vomiting.
The Stage 2 disinfection products rule expands the disinfection products to include bromate. The EPA has set a MCL of 0.1mg/L and a MCLG of 0 mg/L. From the 2018 edition of the Drinking Water and Health Advisory, the EPA has set a DWEL of 0.14 mg/L. "The 10-4 Cancer Risk: The concentration of a chemical in drinking water corresponding to an excess estimated lifetime cancer risk of 1 in 10,000, is 0.005 mg/L and the EPA considers bromate a probable human carcinogen.
One-Day HA: The concentration of a chemical in drinking water that is not expected to cause any adverse noncarcinogenic effects for up to one day of exposure. The One-Day HA intended to protect a 10-kg child consuming 1 liter of water per day is also 0.8 mg/L.
Ten-Day HA: The concentration of a chemical in drinking water that is not expected to cause any adverse noncarcinogenic effects for up to ten days of exposure. The Ten-Day HA is intended to protect a 10-kg child consuming 1 liter of water per day is 0.8 mg/L.
Bromate is considered by the EPA to be a probable human carcinogen.
You should get your water tested for bromate if you are using a drinking water source that is ozonated.
Level 1 Testing is done with simple observations that an individual can make with their own senses such as sight, smell, and taste. These observations can be readily apparent or can be observed as they change over time. In addition, accessible related information about the home can also be used to narrow down the cause of your water issues.
Bromate does not have a specific taste or odor. The primary way to address issues with bromate would be to be proactive and make sure to measure the level of bromide in water if you're considering an ozonation system and to understand the source of your drinking water.
You may suspect a problem with bromate, if:
Level 2 Testing is Do-It-Yourself testing that can be done in your own home using a Testing Kit. After you’ve done Level 1 Testing, Level 2 Testing can confirm if your observations are correct. If your test results reveal the presence of a contaminant that is cause for concern, you can either proceed to determine the best treatment (see below) or continue to Level 3 Testing.
Unfortunately, there are no good low-cost Level 2 tests for Bromate although it can be an added option to a Level 3 WaterCheck™, or CityCheck™ test (See Level 3 Testing).
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L6-uranium">Note: Uranium less than < 0.030 mg/L</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POU Device System Component)</div>
<div class="product-note in-L6-benzene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-chloroform-trichloromethane">Note: If the concentration is < 0.080 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-ethylbenzene">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-methylene-chloride-dichloromethane-dcm">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-mtbe-methyl-tert-butyl-ether">Note: If the concentration is < 0.07 mg/L</div>
<div class="product-note in-L6-tetrachloroethylene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-trichloroethylene">Note: If the concentration is < 0.004 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-toluene">Note: If the concentration is less than 0.8 mg/L</div>
<div class="product-note in-L6-xylenes">Note: If the concentration is < 1 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-atrazine">Note: If the concentration is < 0.001 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-alachlor">Note: If the concentration is < 0.002 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-glyphosate">Note: If the concentration is < 0.7 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-2-4-d">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-bis-2-ethylhexyl-phthalate">Note: If the concentration is < 0.006 mg/L (POE Device System Component</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POE Device System Component)</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L6-uranium">Note: Uranium less than < 0.030 mg/L</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POU Device System Component)</div>
<div class="product-note in-L6-benzene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-chloroform-trichloromethane">Note: If the concentration is < 0.080 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-ethylbenzene">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-methylene-chloride-dichloromethane-dcm">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-mtbe-methyl-tert-butyl-ether">Note: If the concentration is < 0.07 mg/L</div>
<div class="product-note in-L6-tetrachloroethylene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-trichloroethylene">Note: If the concentration is < 0.004 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-toluene">Note: If the concentration is less than 0.8 mg/L</div>
<div class="product-note in-L6-xylenes">Note: If the concentration is < 1 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-atrazine">Note: If the concentration is < 0.001 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-alachlor">Note: If the concentration is < 0.002 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-glyphosate">Note: If the concentration is < 0.7 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-2-4-d">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-bis-2-ethylhexyl-phthalate">Note: If the concentration is < 0.006 mg/L (POE Device System Component</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POE Device System Component)</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
Level 3 Testing is done through an accredited Water Testing Laboratory. With Level 3 Testing, you can order a testing kit that is used to prepare your sample and submit it to the lab. By utilizing a lab, you have the assurance that a certified water expert had analyzed your water sample. If your test results reveal the presence of a contaminant that is cause for concern, you can either proceed to determine the best treatment options (see below) or continue to Level 4 Testing - Certified Testing.
Some informational water testing kits do include testing for disinfection by-products. Because bromate is more commonly present in water treated with ozone, the kits below have been customized for Bromide testing this application.
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L6-uranium">Note: Uranium less than < 0.030 mg/L</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POU Device System Component)</div>
<div class="product-note in-L6-benzene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-chloroform-trichloromethane">Note: If the concentration is < 0.080 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-ethylbenzene">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-methylene-chloride-dichloromethane-dcm">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-mtbe-methyl-tert-butyl-ether">Note: If the concentration is < 0.07 mg/L</div>
<div class="product-note in-L6-tetrachloroethylene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-trichloroethylene">Note: If the concentration is < 0.004 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-toluene">Note: If the concentration is less than 0.8 mg/L</div>
<div class="product-note in-L6-xylenes">Note: If the concentration is < 1 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-atrazine">Note: If the concentration is < 0.001 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-alachlor">Note: If the concentration is < 0.002 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-glyphosate">Note: If the concentration is < 0.7 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-2-4-d">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-bis-2-ethylhexyl-phthalate">Note: If the concentration is < 0.006 mg/L (POE Device System Component</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POE Device System Component)</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
A Level 4 Certified Test Test uses chain-of-custody with a water professional coming to your home to prepare the water sample and then works with an accredited laboratory in order to certify your test results. This type of testing not only gives you the highest level of assurance in the accuracy of your test results, but can also be used as a document in legal cases. For Baseline Testing, we recommend that you use Certified Testing.
If you are considering certified testing for bromate it may be advisable to also document the pH, total organic carbon content, other disinfection by-products, and the level of bromide and other salts. If you need assistance, please Contact our team.
Bromate can be removed from water using reverse osmosis, granular-activated-carbon, and ultrafiltration. These systems are typically not whole-house units, but point-of-use devices or systems designed to provide for potable water uses only.
For the short term, it may be advisable to install point-of-use granular-activated-carbon filters to reduce the level of bromate and/or to use a bottled water source for potable water needs.
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L6-uranium">Note: Uranium less than < 0.030 mg/L</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POU Device System Component)</div>
<div class="product-note in-L6-benzene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-chloroform-trichloromethane">Note: If the concentration is < 0.080 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-ethylbenzene">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-methylene-chloride-dichloromethane-dcm">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-mtbe-methyl-tert-butyl-ether">Note: If the concentration is < 0.07 mg/L</div>
<div class="product-note in-L6-tetrachloroethylene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-trichloroethylene">Note: If the concentration is < 0.004 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-toluene">Note: If the concentration is less than 0.8 mg/L</div>
<div class="product-note in-L6-xylenes">Note: If the concentration is < 1 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-atrazine">Note: If the concentration is < 0.001 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-alachlor">Note: If the concentration is < 0.002 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-glyphosate">Note: If the concentration is < 0.7 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-2-4-d">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-bis-2-ethylhexyl-phthalate">Note: If the concentration is < 0.006 mg/L (POE Device System Component</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POE Device System Component)</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
Submit a Request for Consultation with the KnowYourH20 Team. Contact Us
For the long term, it would be wise to attempt to adjust the treatment system to limit or reduce the amount of bromate that is actually formed. This may require reducing the oxidant concentration, prolonging reaction time, adjusting pH, changing the Alkalinity of the water, and reducing precursors. If you are using chlorine as a disinfectant, it may be wise to check to confirm that the chlorine meets NSF standards and does not have high levels of bromate as a by-product of chlorine production. Regarding treatment, granular-activated-carbon may reduce bromate levels by 50 to 80 % and Reverse Osmosis can reduce bromate by 90%. Because other contaminants can compete for exchange sites or reduce the capacity of a reverse osmosis unit, it is wise to conduct a comprehensive water quality test, to also consider a multiple barrier approach, i.e., not just one technology, and to hire a professional.
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L6-uranium">Note: Uranium less than < 0.030 mg/L</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POU Device System Component)</div>
<div class="product-note in-L6-benzene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-chloroform-trichloromethane">Note: If the concentration is < 0.080 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-ethylbenzene">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-methylene-chloride-dichloromethane-dcm">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-mtbe-methyl-tert-butyl-ether">Note: If the concentration is < 0.07 mg/L</div>
<div class="product-note in-L6-tetrachloroethylene">Note: If the concentration is < 0.005 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-trichloroethylene">Note: If the concentration is < 0.004 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-toluene">Note: If the concentration is less than 0.8 mg/L</div>
<div class="product-note in-L6-xylenes">Note: If the concentration is < 1 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-atrazine">Note: If the concentration is < 0.001 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-alachlor">Note: If the concentration is < 0.002 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-glyphosate">Note: If the concentration is < 0.7 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-2-4-d">Note: If the concentration is < 0.03 mg/L (POE Device System Component)</div>
<div class="product-note in-L6-bis-2-ethylhexyl-phthalate">Note: If the concentration is < 0.006 mg/L (POE Device System Component</div>
<div class="product-note in-L6-bromate">Note: If the concentration is < 0.01 mg/L (POE Device System Component)</div>
<div class="product-note in-L4-methyl-tertiary">Note: Concentrations < 40 ppb</div>
If the concentration is at or over 0.01 mg/L - Recommendation: Seek Advice from a Local Professional (Customized Solution). Contact Us